ARENETHIOLATOCOPPER(I) COMPLEXES AS HOMOGENEOUS CATALYSTS FOR MICHAEL ADDITION-REACTIONS

被引：100

作者：

VANKLAVEREN, M ^{[1
]}

LAMBERT, F ^{[1
]}

EIJKELKAMP, DJFM ^{[1
]}

GROVE, DM ^{[1
]}

VANKOTEN, G ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE RES INST,DEPT MET MEDIATED SYNTH,3584 CH UTRECHT,NETHERLANDS

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 33期

关键词：

D O I：

10.1016/0040-4039(94)88097-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Arenethiolatocopper(I) complexes are shown to be efficient homogeneous catalysts in Michael addition reactions of several Grignard reagents to acyclic enones; the addition products are formed with excellent chemoselectivity (>99%) and good enantioselectivity (76% e.e.).

引用

页码：6135 / 6138

页数：4

共 24 条

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