NO/H2O CLATHRATE FORMATION IN SUB-NANO GRAPHITIC SLIT SPACES

被引：16

作者：

FUJIE, K

MINAGAWA, S

SUZUKI, T

KANEKO, K

机构：

[1] Department of Chemistry, Faculty of Science, Chiba University, Inage-ku, Chiba-shi, 263

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 236卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(95)00238-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activated carbon fiber (ACF) has uniform micropores which can be regarded as graphitic slit spaces. The water adsorption isotherms of ACF with and without preadsorbed NO at 303 K were determined. The characteristic interaction of adsorbed NO with H2O was observed. The desorption of NO during H2O adsorption on the ACF having preadsorbed NO did not proceed only in the P/P-0 (H2O) range of 0.2 to 0.6. The presence of a plateau in the NO desorption isotherm was presumed to be ascribable to a stable H2O-NO clathrate compound formation in the micropore.

引用

页码：427 / 430

页数：4

共 14 条

[1] NON-STOICHIOMETRIC CLATHRATE COMPOUNDS OF WATER .4. KINETICS OF FORMATION OF CLATHRATE PHASES [J].