ALLENE EPOXIDATION - OXIDATIVE CYCLIZATIONS OF ALLENYL ACIDS

被引：21

作者：

CRANDALL, JK

RAMBO, E

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 24期

关键词：

D O I：

10.1021/jo00311a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: The dimethyldioxirane oxidation of a series of allenyl carboxylic acids with varying numbers (0–3) of carbons between the two functions leads to highly functionalized lactones derived from cyclization of intermediate diepoxides. The regiochemistry is generally controlled so as to give 7- and δ-lactones. © 1990, American Chemical Society. All rights reserved.

引用

页码：5929 / 5930

页数：2

共 18 条

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[6] ALLENE EPOXIDATION - EFFICIENT SYNTHESIS AND SYNTHETIC CONVERSIONS OF 1,4-DIOXASPIRO[2.2]PENTANES
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[7] ALLENE EPOXIDATION - OXIDATIVE CYCLIZATIONS OF ALLENYL ALCOHOLS
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[8] REDUCTIVE CYCLIZATIONS OF ALLENIC KETONES BY DISSOLVING METALS
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[9] ALLENE EPOXIDATION - ISOLATION OF REACTIVE INTERMEDIATES FROM HINDERED ALLENES
CRANDALL, JK
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KOMIN, JB
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