BIS(P,P-DI-TERT-BUTYLPHOSPHINIC-N-ISOPROPYLAMIDATO-N,O)NICKEL(II), A PARAMAGNETIC PLANAR COMPLEX

被引：20

作者：

FROMMEL, T ^{[1
]}

PETERS, W ^{[1
]}

WUNDERLICH, H ^{[1
]}

KUCHEN, W ^{[1
]}

机构：

[1] UNIV DUSSELDORF,INST ANORGAN CHEM & STRUKT CHEM,UNIV STR 1,W-4000 DUSSELDORF 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 05期

关键词：

D O I：

10.1002/anie.199206121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Against all previous experience for Ni(II) complexes chemistry, planarity is not necessarily linked with diamagnetism. An X-ray structure determination of the title complex 1 revealed that the Ni(II) center is in a strictly planar environment. Yet in the solid state and in solution. 1 shows Curie-Weiss behavior and has a magnetic moment, as expected for tetrahedral Ni(II) complexes.

引用

页码：612 / 613

页数：2

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