MICROEMULSION POLYMERIZATION OF STYRENE

被引：33

作者：

GAN, LM ^{[1
]}

CHEW, CH ^{[1
]}

LYE, I ^{[1
]}

IMAE, T ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT CHEM,NAGOYA,AICHI 464,JAPAN

来源：

POLYMER BULLETIN | 1991年 / 25卷 / 02期

关键词：

D O I：

10.1007/BF00310791

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microemulsion polymerization of styrene initiated by water-soluble potassium persulphate produced microlatexes which are stable at room temperature even after a year of preparation. The effects of initiator concentration, polymerization temperature, as well as monomer concentration on the polymerization kinetics and molecular weight distribution were investigated. The microemulsion polymerization rate shows only two reaction intervals as a function of monomer conversion. It increased to a maximum at about 20% conversion and then decreased on further polymerization. The final latexes obtained are characterized by high molecular weight of polystyrene (MBARw: 5-10x10(6)) and small particle diameter (D: 20-40 nm). It is calculated that each latex consists of two to four polystyrene chains.

引用

页码：193 / 198

页数：6

共 12 条

[1] POLYMERIZED MICRO-EMULSIONS [J].