ON THE STRUCTURAL ORIGINS OF SOLID-STATE URETHANE POLYDIACETYLENE THERMOCHROMISM - THERMAL AND STRUCTURAL-PROPERTIES OF IPUDO MONOMER AND POLYMER

被引：32

作者：

HANKIN, SHW ^{[1
]}

DOWNEY, MJ ^{[1
]}

SANDMAN, DJ ^{[1
]}

机构：

[1] GTE LABS INC,40 SYLVAN RD,WALTHAM,MA 02254

来源：

POLYMER | 1992年 / 33卷 / 23期

关键词：

POLYDIACETYLENE; THERMOCHROMIC TRANSITION; THERMAL ANALYSIS; X-RAY DIFFRACTION;

D O I：

10.1016/0032-3861(92)90066-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Calorimetric studies of the diacetylene monomer bis-isopropylurethane of 5,7-dodecadiyn-1,12-diol, synthesized by a new method, and the polydiacetylene (PDA) from this monomer (PDA-IPUDO) rule out the possibility that monomer melting plays a significant role in the thermochromic phase transition of this polymer. X-ray powder diffraction studies at room temperature and 150 +/- 5-degrees-C reveal that the structural changes which occur in the course of the endothermic thermochromic phase transition are analogous to those of a related PDA.

引用

页码：5098 / 5101

页数：4

共 27 条

[1] REVERSIBLE COLOR CHANGES OF POLYDIACETYLENE INDUCED BY MONOMER SOLID-PHASE TRANSITION
ARAYA, K
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (02) : 730 - 731
[2] POINT-DEFECTS IN FULLY CONJUGATED POLYMERS
BAUGHMAN, RH
CHANCE, RR
[J]. JOURNAL OF APPLIED PHYSICS, 1976, 47 (10) : 4295 - 4300
[3] ABINITIO EFFECTIVE HAMILTONIAN STUDY OF THE ELECTRONIC-PROPERTIES OF CONJUGATED POLYMERS
BREDAS, JL
CHANCE, RR
BAUGHMAN, RH
SILBEY, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (07) : 3673 - 3678
[4] THERMOCHROMISM IN A POLYDIACETYLENE CRYSTAL
CHANCE, RR
BAUGHMAN, RH
MULLER, H
ECKHARDT, CJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (08) : 3616 - 3618
[5] CHANCE RR, 1987, CRYSTALLOGRAPHICALLY, P140
[6] DOWNEY MJ, 1988, MAKROMOL CHEM, V189, P1189
[7] THERMAL EFFECTS ON THE OPTICAL-SPECTRA OF A POLYDIACETYLENE - POLY(1,2-BIS[4-(ISOPROPYLCARBAMOYLOXY)-NORMAL-BUTYL]-1-BUTEN-3-YNYLENE)
ECKHARDT, H
ECKHARDT, CJ
YEE, KC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (12) : 5498 - 5502
[8] RESONANCE RAMAN STUDY OF THERMOCHROMIC PHASE-TRANSITION OF A POLYDIACETYLENE
EXARHOS, GJ
RISEN, WM
BAUGHMAN, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) : 481 - 487
[9] HANKIN SHW, 1992, MATER RES SOC SYMP P, V247, P661, DOI 10.1557/PROC-247-661
[10] INGANAS O, 1989, SYNTHETIC MET, V28, pC377, DOI 10.1016/0379-6779(89)90549-3

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