ELECTROCHEMICAL SYNTHESIS OF A REDOX-ACTIVE POLYMER-BASED ON BUCKMINSTERFULLERENE EPOXIDE

被引：82

作者：

FEDURCO, M ^{[1
]}

COSTA, DA ^{[1
]}

BALCH, AL ^{[1
]}

FAWCETT, WR ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 02期

关键词：

ELECTROCHEMISTRY; FULLERENES; ORGANIC CONDUCTORS; POLYMERS;

D O I：

10.1002/anie.199501941

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under cathodic conditions a polymer film forms on an electrode when C60O is first reduced in the presence of Bu4NClO4 in toluene/acetonitrile and then oxidized. Films with thicknesses of up to 3 μm can be produced by repeated cyclic voltammetry. Evidence for ionic as well as electronic conductivity of this fullerene polymer is also provided. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：194 / 196

页数：3

共 13 条

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