PHASE-STRUCTURE OF CARBON SUPPORTED PALLADIUM COPPER-CATALYSTS

被引:8
作者
MALLAT, T
SZABO, S
PETRO, J
机构
[1] HUNGARIAN ACAD SCI,CENT RES INST CHEM,H-1525 BUDAPEST,HUNGARY
[2] TECH UNIV BUDAPEST,DEPT ORGAN CHEM TECHNOL,H-1521 BUDAPEST,HUNGARY
关键词
D O I
10.1016/0169-4332(90)90029-Y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The phase structure of 7%Pd-3%Cu on activated carbon catalysts was studied by potentiodynamic polarization and XRD methods. Unalloyed Pd, Pd-rich disordered alloy, unalloyed Cu and Cu3Pd phases and adsorbed Cu have been detected, depending on the preparation methods. Activity in hydrogenation reactions was attributed to the Pd-rich disordered alloy phase. © 1990.
引用
收藏
页码:309 / 313
页数:5
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