ELECTROSYNTHESIS OF TRANSITION-METAL FLUORO COMPLEXES BY THE DISSOLUTION OF A SACRIFICIAL METAL ANODE

被引：7

作者：

CHAKRAVORTI, MC

SUBRAHMANYAM, GVB

BANDYOPADHYAY, D

机构：

[1] Department of Chemistry, Indian Institute of Technology, Kharagpur

来源：

POLYHEDRON | 1991年 / 10卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)81335-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general method for the electrosynthesis of anionic fluoro complexes of transition metals has been developed by the oxidation of sacrificial metal anodes in 20% HF medium at room temperature and at an applied potential of 2-8 V. Some mixed-valent complexes, e.g. Fe2F5.2H2O and Fe2F5.7H2O, have also been obtained by the same method. K2[MnF5].H2O was obtained by subsequent electrolytic oxidation of the Mn(II) fluoro complex obtained in situ in the first step. The method is rapid and gives a good yield with high purity.

引用

页码：2605 / 2609

页数：5

共 22 条

[1] DIRECT SYNTHESIS OF ALKALI TRIFLUOROCOBALTATE(II) MONOHYDRATES, NH4[COF3].H2O, NA[COF3].H2O, OR K[COF3].H2O - 1ST SYNTHESIS AND STRUCTURAL ASSESSMENT OF MIXED-LIGAND FLUORO COMPLEXES OF COBALT(II), [CO(NH3)4F2] AND NH4[COF(SO4)(H2O)2], NA[COF(SO4)(H2O)2], OR K[COF(SO4)(H2O)2] [J].

BHATTACHARJEE, MN ;

CHAUDHURI, MK ;

DEVI, M ;

YHOME, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (05) :1055-1057

[2] A RAPID AND DIRECT ELECTROCHEMICAL SYNTHESIS OF K2[MOOF5] [J].

CHAKRAVORTI, MC ;

BANDYOPADHYAY, D .

POLYHEDRON, 1988, 7 (12) :1135-1136

[3]

CHAKRAVORTI MC, UNPUB

[4]

CHARLOT G, 1957, QUANTITATIVE INORGAN, P425

[5]

COLTON R, 1969, HALIDES 1ST ROW TRAN, P194

[6]

EDWARDS AJ, 1971, J CHEM SOC A, P2654

[7]

EVANS DF, 1967, J CHEM SOC A, P698

[8] MIXED-VALENT IRON FLUORIDE HYDRATES AND THEIR THERMAL-DECOMPOSITION PRODUCTS [J].

GALLAGHER, KJ ;

OTTAWAY, MR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (11) :978-982

[9]

HALL W, 1977, INORG CHEM, V10, P1884

[10]

KONEV VA, 1986, ZH NEORG KHIM, V31, P838

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