A SIMPLE DEPENDENCE OF THE CAPACITY RATIO ON THE COMPOSITION OF THE MOBILE PHASE IN LIQUID-SOLID CHROMATOGRAPHY

被引：6

作者：

BOROWKO, M

机构：

[1] M. Curie-Sklodowska Univ, Lublin, Pol, M. Curie-Sklodowska Univ, Lublin, Pol

来源：

JOURNAL OF LIQUID CHROMATOGRAPHY | 1986年 / 9卷 / 09期

关键词：

CHEMICAL ANALYSIS - Equipment - SOLVENTS - Applications;

D O I：

10.1080/01483918608078746

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The general dependence of the capacity ratio on the composition of the multicomponent mobile phase is presented. The effects connected with difference of molecular sizes of solutes and solvents are considered. A simple linear dependence for the binary mobile phase is proposed and tested on experimental data.

引用

收藏

页码：1837 / 1847

页数：11

相关论文

共 16 条

[1]

[Anonymous], 2021, AACR ANN M APR MAY

[2] ASSOCIATION EFFECTS IN ADSORPTION FROM MULTICOMPONENT SOLUTIONS ON SOLIDS AND LIQUID ADSORPTION CHROMATOGRAPHY [J].

BOROWKO, M ;

JARONIEC, M .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :363-372

[3] LIQUID ADSORPTION CHROMATOGRAPHY WITH MULTICOMPONENT MOBILE PHASE [J].

BOROWKO, M .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1984, 102 (02) :519-526

[4] CURRENT STATE IN ADSORPTION FROM MULTICOMPONENT SOLUTIONS OF NON-ELECTROLYTES ON SOLIDS [J].

BOROWKO, M ;

JARONIEC, M .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1983, 19 (1-2) :137-177

[5]

BOROWKO M, UNPUB J LIQUID CHROM

[6]

EVERETT DH, 1965, T FARADAY SOC, V61, P2487

[7] GRADIENT ELUTION IN LIQUID-CHROMATOGRAPHY .1. INFLUENCE OF COMPOSITION OF MOBILE PHASE ON CAPACITY RATIO (RETENTION VOLUME, BAND WIDTH, AND RESOLUTION) IN ISOCRATIC ELUTION - THEORETICAL CONSIDERATIONS [J].

JANDERA, P ;

CHURACEK, J .

JOURNAL OF CHROMATOGRAPHY, 1974, 91 (APR24) :207-221

[8] APPLICATION OF EXCESS ADSORPTION DATA MEASURED FOR COMPONENTS OF THE MOBILE PHASE FOR CHARACTERIZING CHROMATOGRAPHIC SYSTEMS [J].

JARONIEC, M ;

OSCIKMENDYK, B .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :1277-1284

[9] LIQUID ADSORPTION CHROMATOGRAPHY WITH MIXED MOBILE PHASES .3. INFLUENCE OF MOLECULAR AREAS OF SOLVENTS AND CHROMATOGRAPHED SUBSTANCES ON THE CAPACITY RATIO [J].

JARONIEC, M ;

ROZYLO, JK ;

OSCIKMENDYK, B .

JOURNAL OF CHROMATOGRAPHY, 1979, 179 (02) :237-245

[10] DEPENDENCE OF CAPACITY RATIO ON MOBILE PHASE COMPOSITION IN LIQUID ADSORPTION CHROMATOGRAPHY [J].

JARONIEC, M ;

NARKIEWICZ, J ;

BOROWKO, M .

CHROMATOGRAPHIA, 1978, 11 (10) :581-585