APPLICATION OF N,S-CHELATING CHIRAL ZINC BIS(ARENETHIOLATE) COMPLEXES AS NEW PRECURSOR CATALYSTS IN THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES

被引：74

作者：

RIJNBERG, E ^{[1
]}

JASTRZEBSKI, JTBH ^{[1
]}

JANSSEN, MD ^{[1
]}

BOERSMA, J ^{[1
]}

VANKOTEN, G ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE INST,DEPT MET MEDIATED SYNTH,3584 CH UTRECHT,NETHERLANDS

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)78262-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of diethylzinc to aldehydes in the presence of a catalytic amount of enantiomerically pure N,S-chelated bis{2-[(R)-1-(dimethylamino)ethyl]phenylthiolato}zinc afforded the corresponding secondary alcohols in neatly quantitative yields with optical purities of up to 99 % e.e. under mild reaction conditions.

引用

页码：6521 / 6524

页数：4

共 14 条

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