OPTICAL EFFECTS IN THE IR REFLECTION-ABSORPTION SPECTRA OF THIN WATER-ICE FILMS ON METAL SUBSTRATES

被引：29

作者：

HORN, AB ^{[1
]}

BANHAM, SF ^{[1
]}

MCCOUSTRA, MRS ^{[1
]}

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 21期

关键词：

D O I：

10.1039/ft9959104005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of film thickness upon the shape of the OH stretching band of thin films of water ice on a gold substrate has been analysed using classical optics. The structure observed in the OH stretching band of films with thicknesses comparable to the wavelength of the IR radiation arises because of a combination of an increased specularly reflected component, an s-polarised component and a relaxation of the metal surface selection rule.

引用

页码：4005 / 4008

页数：4

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