LIQUID-CHROMATOGRAPHIC SEPARATION OF GEOMETRICAL ISOMERS USING SPHERICAL CARBON PACKINGS PREPARED FROM SPHERICAL CELLULOSE PARTICLES

被引：7

作者：

HIRAYAMA, C

NAGAOKA, S

MATSUMOTO, T

IHARA, H

HONBO, J

KURISAKI, H

IKEGAMI, S

机构：

[1] CHISSO CO LTD,CHIYODA KU,TOKYO 100,JAPAN

[2] TOKAI CARBON CO LTD,MINATO KU,TOKYO 107,JAPAN

来源：

JOURNAL OF LIQUID CHROMATOGRAPHY | 1995年 / 18卷 / 08期

关键词：

D O I：

10.1080/10826079508009291

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The packings of spherical carbon beads were prepared by graphitizing the spherical cellulose particles. A types of carbon spherical packings were obtained by various degrees of graphitization. These packings were characterized by examining their chromatographic properties. The higher the degree of graphitization is, the higher the pi-electron recognition became, although there was no change in the selection for a methylene group. The mechanism for recognizing the pi-electron and the steric selectivity is described and discussed.

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页码：1509 / 1520

页数：12

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