[(RE2CL4(DPPM)2)2(MU-TCNQ)], A NOVEL CHARGE-TRANSFER COMPLEX DERIVED FROM A DONOR WITH A METAL-METAL MULTIPLE BOND

被引：52

作者：

BARTLEY, SL

DUNBAR, KR

机构：

[1] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

[2] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 04期

关键词：

D O I：

10.1002/anie.199104481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Black crystals of the title complex are obtained by slow diffusion of THF solutions of [Re2Cl4(dppm)2] (Re = Re) and tetracyanoquinodimethane (TCNQ). Although their conductivity is only ca. 10(-5) S cm-1, the magnetic and structural features of this charge transfer complex are remarkable. The bridging of two metal complexes by a TCNQ unit is without precedent. The concept of using metal-metal multiple-bond systems as donors for inorganic/organic CT complexes appears viable.

引用

页码：448 / 450

页数：3

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