LINEAR CU-OH-CU - MAGNETIC SILENCE FOR DICOPPER(II) IN TRIGONAL BIPYRAMIDAL COORDINATION GEOMETRY

被引：42

作者：

HARDING, CJ

MCKEE, V

NELSON, J

LU, Q

机构：

[1] QUEENS UNIV BELFAST,DEPT CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

[2] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 23期

关键词：

D O I：

10.1039/c39930001768

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dicopper(II) mu-hydroxo cryptate with trigonal bipyramidal copper coordination geometry and linear Cu-O(H)-Cu bridge exhibits virtual diamagnetism arising from efficient antiferromagnetic exchange between d(z)2 magnetic orbitals mediated via the 2p(z) orbital of the hydroxo bridge.

引用

页码：1768 / 1770

页数：3

共 15 条

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