EXCITED-STATE DIPOLE-MOMENTS FROM AN EFFICIENT ANALYSIS OF SOLVATOCHROMIC STOKES SHIFT DATA

被引：158

作者：

RAVI, M ^{[1
]}

SAMANTA, A ^{[1
]}

RADHAKRISHNAN, TP ^{[1
]}

机构：

[1] UNIV HYDERABAD,SCH CHEM,HYDERABAD 500134,ANDHRA PRADESH,INDIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 37期

关键词：

D O I：

10.1021/j100088a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is shown that the solvatochromism of Stokes shifts has superior correlation with the solvent polarity function E(T)(N), and the theoretical basis for this is analyzed. The estimation of reliable excited state dipole moments from this correlation as well as the practical advantage of the method in terms of the possibility of employing mixed solvents is demonstrated.

引用

页码：9133 / 9136

页数：4

共 29 条

[1]

BARTOSZEWICZ B, 1971, B ACAD POL SCI SMAP, V19, P249

[2] ZUR THEORIE DES EINFLUSSES VON LOSUNGSMITTELN AUF DIE ELEKTROENSPEKTREN DER MOLEKULE [J].

BILOT, L ;

KAWSKI, A .

ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1962, A 17 (07) :621-&

[3]

Chemia D. S., 1987, NONLINEAR OPTICAL PR

[4] DIALKYLAMINOBENZONITRILES AS FLUORESCENCE POLARITY PROBES FOR AQUEOUS-SOLUTIONS OF CYCLODEXTRINS [J].

COX, GS ;

HAUPTMAN, PJ ;

TURRO, NJ .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1984, 39 (05) :597-601

[5] DIE BEEINFLUSSUNG DER FLUORESZENZ VON MOLEKULEN DURCH EIN AUSSERES ELEKTRISCHES FELD .2. BESTIMMUNG VON DIPOLMOMENTEN ANGEREGTER MOLEKULE [J].

CZEKALLA, J ;

LIPTAY, W ;

MEYER, KO .

BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1963, 67 (05) :465-470

[6]

CZEKALLA J, 1961, CHIMIA, V15, P26

[7]

CZEKALLA J, 1960, Z ELEKTROCHEM, V64, P1221

[8]

DIMORTH K, 1963, LIEBIGS ANN CHEM, V1, P661

[9]

Haas M. P. D., 1982, CHEM PHYS, V73, P35

[10] THERMOCHROMIC SHIFTS OF SOME MOLECULAR AND EXCIPLEX FLUORESCENCE-SPECTRA [J].

HAGAN, T ;

PILLOUD, D ;

SUPPAN, P .

CHEMICAL PHYSICS LETTERS, 1987, 139 (06) :499-502

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