SPREADING OF A DROP BETWEEN A SOLID AND A VISCOUS POLYMER

被引:18
作者
BROCHARDWYART, F
DEGENNES, PG
机构
[1] COLL FRANCE,11 PL M BERTHELOT,F-75231 PARIS 05,FRANCE
[2] INST CURIE,PSI,F-75005 PARIS,FRANCE
关键词
D O I
10.1021/la00019a069
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We consider, for instance, a water droplet (viscosity eta(w)) which tends to wet completely the interface between a hydrophilic solid and a polymer melt (of high viscosity eta(p)). From the Huh-Scriven analysis, we expect two regimes of spreading: (1) when the dynamic contact angle theta is larger than R-1/3 (where R = eta(p)/eta(w)), the velocity U of the contact line should be independent of theta and the radius of the wet patch Q should increase linearly in time rho = Ut; (2) when theta < R-1/3, we return to the standard Tanner law U approximately theta3 and rho approximately t1/10.
引用
收藏
页码:2440 / 2443
页数:4
相关论文
共 10 条