CHIRAL 2-ALKOXY-1,3-BUTADIENES - SYNTHESIS AND FACE-SELECTIVITY IN DIELS-ALDER REACTIONS

被引：12

作者：

BARLUENGA, J

TOMAS, M

SUAREZSOBRINO, A

LOPEZ, LA

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001785

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral 2-alkoxy-1,3-butadienes are prepared from chiral alcohols, prop-2-ynyltriphenylphosphonium bromide and aldehydes; they undergo [4 + 2] cycloadditions to carbo- and hetero-dienophiles with moderate to high face-selectivity.

引用

页码：1785 / 1786

页数：2

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