MERCURY-PHOTOSENSITIZED SULFINATION, HYDROSULFINATION, AND CARBONYLATION OF HYDROCARBONS - ALKANE AND ALKENE CONVERSION TO SULFONIC-ACIDS, KETONES, AND ALDEHYDES

被引：45

作者：

FERGUSON, RR ^{[1
]}

CRABTREE, RH ^{[1
]}

机构：

[1] YALE UNIV,DEPT CHEM,225 PROSPECT ST,NEW HAVEN,CT 06511

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 19期

关键词：

D O I：

10.1021/jo00019a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mercury-photosensitized sulfination of alkanes, RH, with SO2 forms sulfinic acids (RSOOH) and sulfinate esters (RSOOR) in high conversion and yield; oxidation of the mixture produces RSO2OH in high yield. Mercury-photosensitized hydrosulfination of alkenes with H2 and SO2 gives RSO2OH after oxidative workup. Mercury-photosensitized carbonylation of alkanes with CO gives RCHO and R2CO.

引用

页码：5503 / 5510

页数：8

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