STRUCTURAL STUDY OF PROTON ELECTROCHEMICAL INTERCALATION IN MANGANESE-DIOXIDE

被引：8

作者：

RIPERT, M

POINSIGNON, C

CHABRE, Y

PANNETIER, J

机构：

[1] UNIV JOSEPH FOURIER GRENOBLE 1,SPECTROMETRIE PHYS LAB,F-38402 ST MARTIN DHERES,FRANCE

[2] ECOLE NATL SUPER ELECTROCHIM & ELECTROMET GRENOBLE,INST NATL POLYTECH GRENOBLE,F-38402 ST MARTIN DHERES,FRANCE

来源：

PHASE TRANSITIONS | 1991年 / 32卷 / 1-4期

关键词：

D O I：

10.1080/01411599108219177

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A comprehensive structural model of y/ε-MnO2 is proposed. It allows a quantitative characterization of chemically and electrochemically prepared manganese dioxide, provides a mechanism for the proton intercalation process and explains the (essentially) structural origin of the non-reversibility of the pro-ton/MnO2 batteries. © 1991, Taylor & Francis Group. All rights reserved.

引用

页码：205 / 209

页数：5

共 3 条

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DEWOLFF, PM .

ACTA CRYSTALLOGRAPHICA, 1959, 12 (04) :341-&

[2] ON THE MANGANESE-DIOXIDE ELECTRODE .5. THE EVIDENCE INDICATING THE PRESENCE OF 2 SOLID-SOLUTIONS IN THE RANGE MNO2-MNO1.5 WITH GAMMA-MNO2 AS ONE END MEMBER [J].

MASKELL, WC ;

SHAW, JAE ;

TYE, FL .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1982, 12 (01) :101-108

[3] ELECTRODEPOSITED MANGANESE-DIOXIDE WITH PREFERRED CRYSTAL-GROWTH [J].

PREISLER, E .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1976, 6 (04) :301-310

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