REACTION BETWEEN BIS(BENZYL)TETRAISOPROPOXYDITUNGSTEN(W=W) AND BUT-2-YNE - W2(CH2PH)2(OPRI)4(ETA-2-C2ME2)2 AND W2(H)(OPRI)4(MU-CPH)(MU-C4ME4) - A TERMINAL METAL HYDRIDE WITH H-1-NMR RESONANCE 20 PPM DOWNFIELD OF ME4SI

被引：27

作者：

CHISHOLM, MH ^{[1
]}

EICHHORN, BW ^{[1
]}

HUFFMAN, JC ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1985年 / 13期

关键词：

D O I：

10.1039/c39850000861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：861 / 863

页数：3

共 17 条

[1] THE TETRADECAISOPROPOXYDIHYDRIDOTETRATUNGSTEN STORY
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[4] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .4. ALKYNE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES AND EVIDENCE FOR AN EQUILIBRIUM BETWEEN DIMETALLATETRAHEDRANE AND METHYLIDYNEMETAL COMPLEXES - W2(MU-C2H2)REVERSIBLE2W=CH
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[5] METAL METAL BONDS AND METAL-CARBON BONDS IN THE CHEMISTRY OF MOLYBDENUM AND TUNGSTEN ALKOXIDES
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[6] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .5. COUPLING OF ALKYNE LIGANDS IN REACTIONS INVOLVING DITUNGSTEN HEXAALKOXIDES - AN ALTERNATIVE TO THE METATHESIS REACTION M=M+-C=C--]2M=C
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[7] A NEW STRUCTURE TYPE FOR A 6-ELECTRON TRIANGULO TUNGSTEN CLUSTER - W3(MU-3-CME)(MU-O-I-PR)3(O-I-PR)6
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[J]. INORGANIC CHEMISTRY, 1984, 23 (23) : 3683 - 3684
[8] THE REMARKABLE ROLE OF STERIC FACTORS IN THE REACTIONS OF ALKYNES (HC=CH AND MEC=CME) WITH DITUNGSTEN HEXA-ALKOXIDES - CRYSTAL AND MOLECULAR-STRUCTURES OF W2(OPRI)6(PY)2(MU-C2H2), W2(OCH2BU-TERT)6(PY)2(MU-C2ME2), AND W2(OPRI)6(MU-C4R4)(C2R2), WHERE R = H AND ME (PY = PYRIDINE)
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[9] REACTIONS OF HEXA-TERT-BUTOXYDITUNGSTEN(W=W) WITH DIPHENYLACETYLENE - SYNTHESES AND STRUCTURES OF W2(OCME3)4(MU-C6H5C)2 AND W2(OCME3)4(C6H5CCC6H5)2
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