BISMUTH(III) CHLORIDE ALUMINUM-PROMOTED ALKYLATIONS OF IMMONIUM CATIONS TO AMINES IN AQUEOUS-MEDIA - UNSTABILIZED CARBANION EQUIVALENTS FOR USE IN THE PRESENCE OF WATER

被引：42

作者：

KATRITZKY, AR

SHOBANA, N

HARRIS, PA

机构：

[1] Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1021/om00039a049

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of bismuth(III) chloride-metallic aluminum, allyl, propargyl, benzyl, and methyl halides react with a large range of 1-(aminoalkyl)benzotriazoles at room temperature in THF-water to give the corresponding homoalkylated amines in high yields. 1-(Amidoalkyl)benzotriazoles derived from benzaldehyde are also successfully converted under these conditions into N-substituted amides.

引用

页码：1381 / 1384

页数：4

共 34 条

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