TRANSFORMATION OF THE BIS(TRIMETHYLSILYL)METHYL INTO A BETA-DIKETINIMATO LIGAND - THE X-RAY STRUCTURE OF [LI(L'L')](2), SNCL(ME)(2)(L'L') AND SNCL(ME)(2)(LL),[ L'L'=N(R)C(PH)C(H)C(PH)NR, LL=N(H)C(PH)C(H)C(PH)NH, R=SIME(3))

被引：132

作者：

HITCHCOCK, PB ^{[1
]}

LAPPERT, MF ^{[1
]}

LIU, DS ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期

关键词：

D O I：

10.1039/c39940001699

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of MCHR(2) with ArCN yielded [M(L'L')](2)[R = SiMe(3); M = Li and L'L' = N(R)C(Ar)C(H)C(Ar)NR (Ar = Ph 1a or C(6)H(4)Me-4 1b), or M = K and Ar = Ph 1c]; 1a or 1c was converted into CH2(L'L'-C,C)(2) 2a, L'L'H 2c and SnCl(Me)(2)(L'L') 3a by treatment with CH2Br2, (CH2Br)(2) or H2O, and SnCl(2)Me(2) or SnClMe(3), respectively; and 3a upon hydrolysis gave ShCl(Me)(2)(LL) 3b [LL = N(H)C(Ph)C(H)C(Ph)NH], X-ray data being provided for 1a, 3a and 3b.

引用

页码：1699 / 1700

页数：2

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