MASS DISTRIBUTIONS OF NEGATIVE CLUSTER IONS OF SODIUM-OXIDE

被引：10

作者：

NAKAJIMA, A

SUGIOKA, T

HOSHINO, K

KAYA, K

机构：

[1] Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama, 223, 3-14-1 Hiyoshi, Kohoku-ku

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 189卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(92)85231-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Negative cluster ions of sodium oxide, NanOm- (m = 1 and 2), were generated by laser vaporization of a sodium rod, and their mass distribution was measured. In the mass spectra, a number of intense peaks compared to neighbors were observed; in NanO1-, the "magic numbers" were observed at n = 9, 21, 27, 35, 41, and 59, and in NanO2-, they were observed at n = 11, 17, 23, 29, 37, 43, and 61. Compared with the magic numbers predicted by the jellium shell model, two and four sodium atoms are increased for the magic numbers by adding one and two oxygen atom(s), respectively. Therefore, it is concluded that (1) no valence electrons of oxygen atoms contribute to form the electronic shells of clusters, and that (2) two sodium atoms in the NanOm- clusters are bound by one oxygen atom, forming an Na2O unit as a spectator.

引用

页码：455 / 459

页数：5

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