HIGHLY ENANTIOSELECTIVE PROTONATION OF PHOTODIENOLS AN UNUSUAL SUBSTITUENT EFFECT ON THE INDUCED CHIRALITY

被引：59

作者：

PIVA, O ^{[1
]}

PETE, JP ^{[1
]}

机构：

[1] UNIV REIMS,UFR SCI,CNRS,REARRANGEMENTS THERM & PHOTOCHIM LAB,F-51062 REIMS,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)97830-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiosalectivities up to 91% have been reached during the photodeconjugation of α, β -unsaturated esters or lactones using catalytic amounts of new chiral cyclic inductors derived from (+) camphor. Modification of the substitution on the nitrogen of the inductor can reverse the configuration of the new chiral center. © 1990.

引用

页码：5157 / 5160

页数：4

共 22 条

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