2-PHASE NITRATION OF PHENOLS .3. THE NITRATION OF ANISOLE

被引:30
作者
THOMPSON, MJ [1 ]
ZEEGERS, PJ [1 ]
机构
[1] FLINDERS UNIV,BEDFORD PK,SA 5042,AUSTRALIA
关键词
NITRATION; ANISOLE; NITRIC ACID; ORTHO-PARA RATIOS;
D O I
10.1016/S0040-4020(01)96200-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The two-phase nitration procedure previously described for phenols can be modified to lead to successful nitration of anisole but through a different mechanism. The addition of N(III) species is unnecessary and the reaction is not supressed by nitrous acid traps, the presence of which alters the ortho:para ratio.
引用
收藏
页码:8787 / 8790
页数:4
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