THE STABILIZATION OF MONOVALENT COPPER IONS BY COMPLEXATION WITH SATURATED TERTIARY AMINE LIGANDS IN AQUEOUS-SOLUTIONS - THE CASE OF 2,5,9,12-TETRAMETHYL-2,5,9,12-TETRA-AZATRIDECANE

被引：34

作者：

GOLUB, G

COHEN, H

MEYERSTEIN, D

机构：

[1] NUCL RES CTR NEGEV,IL-84190 BEER SHEVA,ISRAEL

[2] BEN GURION UNIV NEGEV,DEPT CHEM,IL-84105 BEER SHEVA,ISRAEL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 05期

关键词：

D O I：

10.1039/c39920000397

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex of copper(I) ions with 2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane in aqueous solutions is stable in the absence of oxygen; this observation indicates that the stabilization of low valent transition metal cations by tertiary tetraazamacrocyclic ligands is due to the hydrophobic nature of these ligands.

引用

页码：397 / 398

页数：2

共 16 条

[1] ELECTROCHEMICAL AND STRUCTURAL STUDIES OF NICKEL(II) COMPLEXES OF N-ALKYLATED CYCLAM LIGANDS - X-RAY STRUCTURES OF TRANS-[NI(C14H32N4)(OH2)2]CL2.2H2O AND [NI(C14H32N4)](O3SCF3)2
BAREFIELD, EK
FREEMAN, GM
VANDERVEER, DG
[J]. INORGANIC CHEMISTRY, 1986, 25 (04) : 552 - 558
[2] TETRAHEDRAL DISTORTION IN PALLADIUM(II) MACROCYCLIC COMPLEXES - THE SINGLE-CRYSTAL X-RAY STRUCTURE OF [PD(TBC)](PF6)2.0.4MENO2 (TBC = 1,4,8,11-TETRABENZYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE)
BLAKE, AJ
GOULD, RO
HYDE, TI
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (22) : 1730 - 1732
[3] STABILIZATION OF MONO-VALENT PALLADIUM BY TETRA-AZA MACROCYCLES
BLAKE, AJ
GOULD, RO
HYDE, TI
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) : 431 - 433
[4] STABILIZATION OF TRANSITION-METAL COMPLEXES IN HIGH OXIDATION-STATES BY MACROCYCLIC TERTIARY-AMINES - ELECTROCHEMICAL GENERATION AND SPECTROSCOPIC PROPERTIES OF NOVEL DIHALOGENO AND PSEUDOHALOGENO TETRAAMINE COMPLEXES OF RUTHENIUM(IV)
CHE, CM
WONG, KY
POON, CK
[J]. INORGANIC CHEMISTRY, 1986, 25 (11) : 1809 - 1813
[5] CIAMPOLINI M, 1986, INORG CHEM, V25, P4135
[6] COTTON FA, 1980, ADV INORGANIC CHEM
[7] THERMODYNAMICS OF COMPLEX FORMATION WITH LINEAR ALIPHATIC TETRAMINES .2. HEATS AND ENTROPIES OF REACTIONS OF 3,7-DIAZANONANE-1,9-DIAMINE WITH HYDROGEN-IONS AND SOME BIVALENT TRANSITION-METAL IONS
FABBRIZZI, L
BARBUCCI, R
PAOLETTI, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (14): : 1529 - +
[8] HIGHER STABILITY-CONSTANTS FOR COMPLEXATION OF LOW VALENT, THAN OF HIGH VALENT, TRANSITION-METAL IONS BY SATURATED TERTIARY AMINE MACROCYCLIC TETRAAZA LIGANDS
GULDI, D
WASGESTIAN, F
ZEIGERSON, E
MEYERSTEIN, D
[J]. INORGANICA CHIMICA ACTA, 1991, 182 (02) : 131 - 133
[9] Icke R. N., 1941, ORG SYNTH, VIII, P723
[10] STABILIZATION OF MONO-VALENT NICKEL IN AQUEOUS-SOLUTIONS BY COMPLEXATION WITH THE BETA-ISOMER OF C-5,12-RACEMIC-1,4,5,7,7,8,11,12,14,14-DECAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE
JUBRAN, N
MEYERSTEIN, D
COHEN, H
[J]. INORGANICA CHIMICA ACTA, 1986, 117 (02) : 129 - 132

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