A SIMPLE WAY TO (+/-)-DIHYDROACTINIDIOLIDE FROM BETA-IONONE RELATED TO THE ENZYMATIC COOXIDATION OF BETA-CAROTENE IN AQUEOUS-SOLUTION

被引：30

作者：

BOSSER, A

PAPLOREY, E

BELIN, JM

机构：

[1] UNIV BOURGOGNE,ENSBANA,BIOTECHNOL LAB,F-21000 DIJON,FRANCE

[2] METAYER AROMAT IND,RECH DEV LAB,F-94500 CHAMPIGNY MARNE,FRANCE

来源：

BIOTECHNOLOGY PROGRESS | 1995年 / 11卷 / 06期

关键词：

D O I：

10.1021/bp00036a013

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

In a previous paper (Bosser and Belin, 1994), it was shown that the co-oxidation of beta-carotene (BC) by xanthine olridase in aqueous solutions at 37 degrees C led to beta-ionone, epoxy-5,6-beta-ionone, and dihydroactinidiolide (DHA). We explain in this article the pathways between the ionone derivatives, and the respective places of each volatile compound in the enzymatic bleaching of BC are discussed. We also propose a simple synthetic way to DHA from commercially available beta-ionone.

引用

页码：689 / 692

页数：4

共 25 条

[1]

Bohme H, 1940, ORG SYNTH, V20, P70

[2] SYNTHESIS OF BETA-IONONE IN AN ALDEHYDE/XANTHINE OXIDASE/BETA-CAROTENE SYSTEM INVOLVING FREE-RADICAL FORMATION [J].