RECENT ADVANCES IN OXYPALLADATION OF ALKENES

被引：12

作者：

HOSOKAWA, T

MURAHASHI, SI

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1995年 / 53卷 / 11期

关键词：

D O I：

10.5059/yukigoseikyokaishi.53.1009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular cyclizations involving oxypalladation as a key step provide useful entries to oxygen-atom containing heterocycles. The oxypalladation process is highly indispensable rout to synthesizing acetals. or ketones. Surveyed in this article is recent progress relevant to these oxidations from both synthetic and mechanistic viewpoints, and particular attention will be paid to the role of molecular oxygen and copper stilts in palladium catalysis.

引用

页码：1009 / 1020

页数：12

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