CAN THE PREEQUILIBRIUM MOLECULAR-COMPLEX IN A REACTIVE MIXTURE OF ETHENE AND CHLORINE BE CHARACTERIZED - AN ANSWER FROM ROTATIONAL SPECTROSCOPY

被引：18

作者：

BLOEMINK, HI ^{[1
]}

HINDS, K ^{[1
]}

LEGON, AC ^{[1
]}

THORN, JC ^{[1
]}

机构：

[1] UNIV EXETER, DEPT CHEM, EXETER EX4 4QD, DEVON, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rotational spectrum of a complex of C-2v symmetry has been detected in a mixture of ethene and molecular chlorine by using a pulsed nozzle, Fourier-transform microwave spectrometer; the Cl-2 molecule lies along the C-2 axis of ethene that is perpendicular to the molecular plane and interacts only weakly with the pi bond.

引用

页码：1321 / 1322

页数：2

共 17 条

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