A new phenylpropanoid glycoside, angoroside A, and a known glycoside, acetoside, were isolated from the roots of Scrophularia scopolii var. scopollii. On the basis of chemical and spectral evidence, angoroside A was shown to be 3,4-dihydroxy-.beta.-phenylethoxy-O-.alpha.-L-arabinopyranosyl-(1.fwdarw. 6)-.alpha.-L-rhamnopyranosyl-(1.fwdarw.3)-4-O-caffeoyl-.beta.-D-glucopyranoside.