FE+-CATALYZED GAS-PHASE OXIDATION OF ETHANE BY N2O

被引：75

作者：

SCHRODER, D ^{[1
]}

SCHWARZ, H ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014311

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transferance of the N2O oxygen atom to a Fe(C2H4)+ ion with formation of the metallacycle 1 is the key step of the title reaction (a). This follows from ion cyclotron resonance experiments as well as from mechanistic and thermochemical considerations. After decomposition of the ''hot'' intermediate 1 to Fe and acetaldehyde a novel catalytic cycle can be initiated [Eq. (a)].

引用

页码：1431 / 1433

页数：3

共 18 条

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