ENANTIOSELECTIVE SYNTHESIS OF THE AB-RING FRAGMENT OF GAMBIERTOXIN-4B - IMPLICATION FOR THE ABSOLUTE-CONFIGURATION OF GAMBIERTOXIN-4B AND CIGUATOXIN

被引：74

作者：

SUZUKI, T

SATO, O

HIRAMA, M

YAMAMOTO, Y

MURATA, M

YASUMOTO, T

HARADA, N

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

[2] TOHOKU UNIV,FAC AGR,SENDAI 981,JAPAN

[3] TOHOKU UNIV,INST CHEM REACT SCI,SENDAI,MIYAGI 980,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 35期

关键词：

CIGUATOXIN; GAMBIERTOXIN; ABSOLUTE CONFIGURATION; CD; ENANTIOSELECTIVE SYNTHESIS;

D O I：

10.1016/0040-4039(91)80025-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5 R configuration.

引用

页码：4505 / 4508

页数：4

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