SR2RUO4-CENTER-DOT-0.25 CO2 AND THE SYNTHESIS AND ELEMENTARY PROPERTIES OF SR3RU2O7

被引：65

作者：

CAVA, RJ ^{[1
]}

ZANDBERGEN, HW ^{[1
]}

KRAJEWSKI, JJ ^{[1
]}

PECK, WF ^{[1
]}

BATLOGG, B ^{[1
]}

CARTER, S ^{[1
]}

FLEMING, RM ^{[1
]}

ZHOU, O ^{[1
]}

RUPP, LW ^{[1
]}

机构：

[1] TECH UNIV DELFT,NATL CTR HIGH RESOLUT ELECTRON MICROSCOPY,DELFT,NETHERLANDS

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 116卷 / 01期

关键词：

D O I：

10.1006/jssc.1995.1195

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis of a new strontium ruthenium oxycarbonate, Sr2RuO4 . 0.25 CO2, and its use to synthesize Sr3Ru2O7, the n = 2 member of the (SrO)(n+1) (RuO2)(n) Ruddlesden-Popper series. Like layered K2NiF4-type Sr2RuO4, and three-dimensional perovskite-type SrRuO3, Sr3Ru2O7 is a metallic conductor. In Sr3Ru2O7, the magnetic moments (d(4), low spin) interact weakly with each other and develop strong antiferromagnetic correlations below 15 K. Small substitutions of Ir for Ru in Sr3Ru2O7 result in a metal-insulator transition. (C) 1995 Academic Press, Inc.

引用

页码：141 / 145

页数：5

共 12 条

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