A GENERAL-APPROACH TO CARBOCYCLIC SUGAR ANALOGS - PREPARATION OF A CARBOCYCLIC ANALOG OF BETA-D-FRUCTOFURANOSE

被引：20

作者：

GAUDINO, JJ ^{[1
]}

WILCOX, CS ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

CARBOHYDRATE RESEARCH | 1990年 / 206卷 / 02期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0008-6215(90)80063-9

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The development and execution of the first examples of a new and general approach to carbocyclic analogs of carbohydrates ("pseudo-sugars") is presented. Complete experimental details for the preparation of the carbocyclic analog of β-d-fructofuranose 6-phosphate are described for the first time. In the conclusion, the success of the synthetic strategy is analyzed and an approach to retrosynthetic analysis based on "unitive synthons" is offered for considerations. © 1990.

引用

页码：233 / 250

页数：18

共 38 条

[1] CARBOCYCLES FROM CARBOHYDRATES - A SIMPLE ROUTE TO AN ENANTIOMERICALLY PURE PROSTAGLANDIN INTERMEDIATE [J].