SYNTHESIS AND CRYSTAL-STRUCTURE OF A PENTANUCLEAR HETEROMETALLIC ACETYLIDE COMPLEX CP2MO2RU3(CO)10(C=CPH)2

被引：19

作者：

HWANG, DK

YUN, C

PENG, SM

LEE, GH

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 389卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85400-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentanuclear heterometallic acetylide complex Cp2Mo2Ru3(CO)10(CCPh)2 (3) was prepared by the reaction of the metal acetylide CpMo(CO)3CCPh with Ru3(CO)12. This complex was characterized by spectroscopic methods and by X-ray single-crystal structure determination. Notable structural features of the new complex 3 include an unusual symmetric pentametallic double butterfly skeleton and a novel μ4-η2 bonding mode for the acetylide ligand. Crystal data for 3: space group P21/c; a 24.119(10), b 20.739(4), c 15.358(3) Å, β 101.68(4)°, Z = 8; final R = 0.038, Rw = 0.034 and GOF = 1.57. © 1990.

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页码：C7 / C11

页数：5

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