MOLECULAR ARCHITECTURE OF COPPER(I) THIOMETALLATE COMPLEXES - EXAMPLE OF A CUBANE WITH AN EXTRA FACE, (NPR4)3[MS4CU4CL5] (M = MO, W)

被引：115

作者：

JEANNIN, Y

SECHERESSE, F

BERNES, S

ROBERT, F

机构：

[1] Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 75252 Paris Cédex 05

来源：

INORGANICA CHIMICA ACTA | 1992年 / 198卷

关键词：

D O I：

10.1016/S0020-1693(00)92393-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thiometallates MS4(2-) (M = Mo, W) form with copper(I) heterobimetallic complexes which are interesting because of the versatility of the structural types obtained. The various structures obtained by addition of copper(I) to MS4(2-) are described and illustrated by examples recently reported in the literature. The synthesis and structural characterization of (NPr4)3[MS4Cu4Cl5] are given together with the connections which exist between 'open' and 'closed' cubane structures.

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页码：493 / 505

页数：13

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