REGIOSELECTIVITY OF RADICAL-INDUCED BOND CLEAVAGES IN EPOXIDES

被引：39

作者：

MURPHY, JA

PATTERSON, CW

机构：

[1] Department of Chemistry, University of Nottingham, Nottingham

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 04期

关键词：

D O I：

10.1039/p19930000405

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical-induced carbon-carbon and carbon-oxygen bond cleavage reactions in a highly substituted epoxide, and in epoxides fused to other rings are reported. Substitution at the site of the developing radical assists C-C bond cleavage. In ring-fused epoxides, C-C bond cleavage was not seen where stereoelectronic factors oppose it.

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页码：405 / 410

页数：6

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