STUDY OF THE TELOMERIZATION REACTION OF A CATIONIC SURFACTANT MONOMER

被引：11

作者：

BOUTEVIN, B

ROBIN, JJ

BOYER, B

ROQUE, JP

SENHAJI, O

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,CHIM APPL LAB,8 RUE ECOLE NORMALE,F-34053 MONTPELLIER 1,FRANCE

[2] UNIV MONTPELLIER 2,CHIM ORGAN PHYS LAB,F-34095 MONTPELLIER 5,FRANCE

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 01期

关键词：

D O I：

10.1002/macp.1994.021950110

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A polymerizable methacrylic surfactant is synthetized from methacryloyl chloride and 11-bromoundecanol. The obtained cationic monomer is telomerized with a fluorinated thiol, and the transfer constant C(T) is calculated. This value is in the same range as transfer constants of classical methacrylic monomers. The obtained k(p)2/k(T) is low because of the long chain ester. Polymers were prepared in homogeneous solution with an average molecular weight of 25000.

引用

页码：129 / 137

页数：9

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