H-1-NMR STUDY OF MAGNETIC ANOMALY IN (BEDT-TTF)(3)CUBR4

被引：8

作者：

TSUCHIYA, R

YOSHIZAKI, S

NAKAMURA, T

TAKAHASHI, T

YAMAURA, J

SUZUKI, K

ENOKI, T

SAITO, G

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN

[2] KYOTO UNIV,DEPT CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

SYNTHETIC METALS | 1995年 / 70卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02721-A

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The H-1-NMR measurements were carried out on the organic conductor, (BEDT-TTF)(3)CuBr4, where strong coupling between a and 3d electrons are expected. The H-1 spin-lattice relaxation rate, T-1(-1), was large about 20 sec(-1) and almost temperature independent above 60 K, indicating the effect of localized magnetic moments. Anomalies at the structural transition (60 K) was small. An antiferromagnetic transition was confirmed: The magnitude of the moment at Cu site was estimated as 0.6-0.7 mu(B). The moment at the Cu site was found to survive in the metallic state under pressure.

引用

页码：967 / 968

页数：2