NOVEL PRODUCTS IN THE CARBONYLATION OF THE TRIPLY BONDED DITUNGSTEN HEXAISOPROPOXIDE DIPYRIDINE ADDUCT .2. PREPARATION AND STRUCTURE OF W2(O-I-PR)6(CO)4, A MOLECULE CONTAINING 2 ATOMS OF THE SAME METALLIC ELEMENT WITH OXIDATION NUMBERS DIFFERING BY 6 UNITS

被引：15

作者：

COTTON, FA ^{[1
]}

SCHWOTZER, W ^{[1
]}

机构：

[1] TEXAS ADM UNIV,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77840

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1983年 / 105卷 / 17期

关键词：

D O I：

10.1021/ja00355a019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：5639 / 5641

页数：3

共 10 条

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[3] REACTIONS OF METAL-TO-METAL MULTIPLE BONDS .6. REVERSIBLE CARBONYLATION OF HEXAKIS(TERT-BUTOXY)DIMOLYBDENUM (M=M) - CARBONYL-BRIDGED METAL-TO-METAL DOUBLE-BOND, MO2(OBU-T)6(CO) (M=M) [J].

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[5]

Cotton F. A., 1982, MULTIPLE BONDS METAL

[6] NOVEL PRODUCTS IN THE CARBONYLATION OF THE TRIPLY BONDED DITUNGSTEN HEXAISOPROPOXIDE DIPYRIDINE ADDUCT .1. SYNTHESIS AND STRUCTURE OF [(I-PRO)3W(MU-CO)(MU-O-I-PR)W(O-I-PR)2PY]2 [J].

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[7] REACTIONS OF MO2(O-I-PR)6 WITH TRANS-WBR(CO)4(CPH) AND PYRIDINE - STRUCTURAL CHARACTERIZATIONS OF WBR(CO)2(PY)2(CPH) AND MO2(O-I-PR)6(PY)2(CO) [J].

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[8] VIBRATIONAL SPECTRA + BONDING IN METAL CARBONYLS .3. FORCE CONSTANTS + ASSIGNMENTS OF CO STRETCHING MODES IN VARIOUS MOLECULES - EVALUATION OF CO BOND ORDERS [J].

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[9]

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[10] BIS-PI-CYCLOPENTADIENYLTUNGSTEN(IV)(BIS-MU-BENZENETHIOLATO)METAL(O)TETRACARBONYLS (PI-C5H5)2W(MU-SC6H5)2M(CO)4,M=CR,MO, OR W [J].

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