DIRECT TRANSFORMATION OF ERGOSTEROL TO (22S,23E)-6-BETA-METHOXY-3-ALPHA,5-CYCLO-5-ALPHA-ERGOST-23-EN-22-OL, A KEY INTERMEDIATE FOR THE SYNTHESIS OF BRASSINOLIDE

被引：30

作者：

ANASTASIA, M ^{[1
]}

ALLEVI, P ^{[1
]}

CIUFFREDA, P ^{[1
]}

FIECCHI, A ^{[1
]}

SCALA, A ^{[1
]}

机构：

[1] UNIV MILAN,SCH MED,DEPT CHEM & BIOCHEM,I-20133 MILAN,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1984年 / 49卷 / 22期

关键词：

D O I：

10.1021/jo00196a038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：4297 / 4300

页数：4

共 17 条

[1] A SIMPLE METHOD FOR THE REDUCTION OF THE 7,8-DOUBLE BOND OF STEROIDAL 5,7-DIENES
ANASTASIA, M
CIUFFREDA, P
FIECCHI, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (20) : 1169 - 1170
[2] SYNTHESIS OF CASTASTERONE AND ITS 22S,23S-ISOMER - 2-PLANT GROWTH-PROMOTING KETONES
ANASTASIA, M
CIUFFREDA, P
DELPUPPO, M
FIECCHI, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1983, (02): : 383 - 386
[3] A NEW SYNTHESIS OF BRASSINO STEROIDS - PLANT-GROWTH PROMOTING STEROIDS
ANASTASIA, M
CIUFFREDA, P
FIECCHI, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1983, (02): : 379 - 382
[4] ANASTASIA M, 1983, Patent No. 21524
[5] BIOSYNTHESIS OF TERPENES AND STEROIDS .5. SYNTHESIS OF ERGOSTA-5,7,22,24(28)-TETRAEN-3BETA-OL, A BIOSYNTHETIC PRECURSOR OF ERGOSTEROL
BARTON, DHR
SHIORI, T
WIDDOWSON, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (10): : 1968 - +
[6] STEREOSELECTIVE SYNTHESIS OF BRASSINOLIDE - A PLANT-GROWTH PROMOTING STEROIDAL LACTONE
FUNG, S
SIDDALL, JB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (21) : 6580 - 6581
[7] UNSATURATED STEROIDS .3. SYNTHESIS OF STEROIDAL 22,24(28)-DIENES, ERGOSTA-5,7,22,24(28)-TETRAEN-3BETA-OL, AND CHOLESTA-5,7,22-TRIEN-3BETA-OL
GARRY, AB
MIDGLEY, JM
WHALLEY, WB
WILKINS, BJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (08): : 809 - 812
[8] BRASSINOLIDE, A PLANT GROWTH-PROMOTING STEROID ISOLATED FROM BRASSICA-NAPUS POLLEN
GROVE, MD
SPENCER, GF
ROHWEDDER, WK
MANDAVA, N
WORLEY, JF
WARTHEN, JD
STEFFENS, GL
FLIPPENANDERSON, JL
COOK, JC
[J]. NATURE, 1979, 281 (5728) : 216 - 217
[9] ISCHIGURO M, 1980, J CHEM SOC CHEM COMM, P962
[10] SYNTHESIS OF (23R)- AND (23S)-METHYLCHOLESTEROL
LI, HT
MASSEY, IJ
SWENSON, DC
DUAX, WL
DJERASSI, C
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (01) : 48 - 54

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