2E[-]4A2 TRANSITION IN CR3+ - K3CO (CN)6 CRYSTALS

被引：33

作者：

CONDRATE, RA

FORSTER, LS

机构：

[1] Department of Chemistry, University of Arizona, Tucson, AZ

[2] Department of Ceramic Science, College of Ceramics, State University of New York, Alfred, NY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 04期

关键词：

D O I：

10.1063/1.1668872

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Analysis of the Cr(III) 2E↔4A2 spectrum in Cr3+ doped K3Co(CN)6 crystals indicates a 2E splitting of 49 cm-1. The very weak 0-0 lines are consistent with a centrosymmetric complex and a magnetic dipole transition. The measured lifetime exceeds 100 msec, greater by a factor of 10 than the lifetime computed from the absorption spectrum.

引用

页码：1514 / &

共 25 条

[1] SPIN FORBIDDEN BANDS IN CR 3 HEXAMINE [J].