IONIC-CONDUCTIVITY OF POLYMER ELECTROLYTES CONTAINING ROOM-TEMPERATURE MOLTEN-SALTS BASED ON PYRIDINIUM HALIDE AND ALUMINUM-CHLORIDE

被引：87

作者：

WATANABE, M ^{[1
]}

YAMADA, S ^{[1
]}

OGATA, N ^{[1
]}

机构：

[1] SOPHIA UNIV,DEPT CHEM,CHIYODA KU,TOKYO 102,JAPAN

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 13-14期

关键词：

POLYMER ELECTROLYTE; ROOM TEMPERATURE MOLTEN SALT; PYRIDINIUM SALT; ALUMINUM CHLORIDE; IONIC CONDUCTIVITY;

D O I：

10.1016/0013-4686(95)00179-I

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Room temperature molten salts consisting of 1-butylpyridinium halide (chloride or bromide) and aluminium chloride have been utilized as electrolytes for a new class of highly conductive polymer electrolytes. Poly(1-butyl-4-vinylpyridinium halides) (chloride and bromide), which are polymer analogues of the pyridinium salts, are compatible with the molten salts to form polymer electrolytes. The addition of small amount of the polypyridinium salts imparts viscoelastic rubbery property to the polymer electrolytes. The ionic conductivity is much influenced by the composition of the polymer electrolytes and temperature, and the high conductivity comparable to that of the molten salts is attained.

引用

页码：2285 / 2288

页数：4

共 18 条

[1] RUBBERY SOLID ELECTROLYTES WITH DOMINANT CATIONIC TRANSPORT AND HIGH AMBIENT CONDUCTIVITY [J].