A NEW AND CONVENIENT ONE-POT SYNTHESIS OF ALPHA,BETA-UNSATURATED TRIFLUOROMETHYL KETONES

被引:28
作者
HUANG, WS [1 ]
YUAN, CY [1 ]
机构
[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 07期
关键词
D O I
10.1039/p19950000741
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Alkylphosphonates react with N-phenyltrifluoroacetimidoyl chloride in the presence of lithium diisopropylamide to afford mixtures which when treated with aldehydes and subjected to acid hydrolysis afford alpha,beta-unsaturated trifluoromethyl ketones.
引用
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页码:741 / 742
页数:2
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