REACTION-RATE CONSTANTS (295 K) FOR (CH2)-C-3 WITH H2S, SO2, AND NO2 - UPPER-BOUNDS FOR RATE CONSTANTS WITH LESS REACTIVE PARTNERS

被引：28

作者：

DARWIN, DC

MOORE, CB

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] LAWRENCE BERKELEY LAB,DIV CHEM SCI,BERKELEY,CA 94720

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 36期

关键词：

D O I：

10.1021/j100036a022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Direct measurements have been made of the reactive removal rate of tripler methylene with H2S, SO2, and NO2, yielding values for the rate constants of (2.0 +/- 0.3) x 10(-12), (4.9 +/- 0.6) x 10(-12), and (6.9 +/- 1.5) x 10(-11) cm(3) molecule(-1) s(-1), respectively. H-2, CO, CO2, N2O, CH3Cl, (CH3)(2)CO, and C6H6 were found to have rate constants less than similar to 10(-14) cm(3) molecule(-1) s(-1).

引用

页码：13467 / 13470

页数：4

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