SYNTHESIS OF ALPHA-SUBSTITUTED ALLYL-STANNANES AND HOMOALLYL-STANNANES BY SELENOXIDE ELIMINATION

被引：13

作者：

JEPHCOTE, VJ ^{[1
]}

THOMAS, EJ ^{[1
]}

机构：

[1] DYSON PERRINS LAB,OXFORD OX1 3QY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 02期

关键词：

D O I：

10.1039/p19910000429

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alpha-methyl-, alpha-phenyl- and alpha,alpha-dimethyl-allylstannanes 20-22 have been prepared by oxidative elimination of the corresponding primary selenides 17-19, and were found to be stable with respect to 1,3-migration of the tributyltin moiety in non-polar solvents (t less-than-or-equal-to 100-degrees-C). Homoallylstannanes 32-34 were the major products obtained by oxidative elimination of the secondary selenides 29-31, with mixtures of regioisomers being obtained from the other secondary selenides investigated.

引用

页码：429 / 434

页数：6

共 35 条

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