REDUCTION OF THE SMALL SUBUNIT OF RIBONUCLEOTIDE REDUCTASE BY DIIMIDE - EVIDENCE FOR THE FORMATION OF THE MIXED-VALENCE FEII-FEIII CENTER

被引：17

作者：

GEREZ, C

GAILLARD, J

LATOUR, JM

FONTECAVE, M

机构：

[1] UNIV JOSEPH FOURIER CHIM RECH,301 RUE CHIM,DOMAINE UNIV,BP 53X,F-38041 GRENOBLE,FRANCE

[2] CEN GRENOBLE,DEPT RECH FONDAMENTALE,DSM,F-38041 GRENOBLE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The diiron(III) center of the protein R2, a subunit of the ribonucleotide reductase, can be efficiently reduced with diimide to the mixed valence Fe(II)/Fe(III) state, which can be detected EPR spectroscopically. A comparison with the spectra of the mixed valence state of hemerythrin suggests that both Fe atoms are only weakly antiferromagnetically coupled, and are bound via a hydroxo bridge.

引用

页码：1135 / 1136

页数：2

共 20 条

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