PHOTOCATALYTIC OXYGENATION OF STRAINED ALICYCLIC ALKENES WITH MU-OXO-BIS[TETRAPHENYLPORPHYRINATOIRON(III)] AND MOLECULAR-OXYGEN

被引：37

作者：

WEBER, L

HAUFE, G

REHOREK, D

HENNIG, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron(III) porphyrins are active catalysts for the photocatalytic epoxidation of strained cyclic alkenes and their methyl substituted derivatives with molecular oxygen.

引用

页码：502 / 503

页数：2

共 14 条

[1]

[Anonymous], 1982, ACS MONOGRAPH

[2]

BERTHOLD T, 1986, Z CHEM, V26, P183

[3] HYDROXYLATION BY CYTOCHROME-P-450 AND METALLOPORPHYRIN MODELS - EVIDENCE FOR ALLYLIC REARRANGEMENT [J].

GROVES, JT ;

SUBRAMANIAN, DV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (07) :2177-2181

[4] REACTIVE IRON PORPHYRIN DERIVATIVES RELATED TO THE CATALYTIC CYCLES OF CYTOCHROME-P-450 AND PEROXIDASE - STUDIES OF THE MECHANISM OF OXYGEN ACTIVATION [J].

GROVES, JT ;

WATANABE, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) :8443-8452

[5] PICOSECOND ABSORPTION STUDIES ON THE EXCITED-STATE OF (MU-OXO)BIS[(TETRAPHENYLPORPHINATO)IRON(III)] [J].

GUEST, CR ;

STRAUB, KD ;

HUTCHINSON, JA ;

RENTZEPIS, PM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (16) :5276-5280

[6]

INCHLEY P, 1989, NEW J CHEM, V13, P669

[7] HOMOLYTIC AND HETEROLYTIC SCISSION OF ORGANIC HYDROPEROXIDES BY (MESO-TETRAPHENYLPORPHINATO)IRON(III) AND ITS RELATION TO OLEFIN EPOXIDATION [J].

LABEQUE, R ;

MARNETT, LJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) :6621-6627

[8] CYTOCHROME-P-450 AND SYNTHETIC MODELS [J].

MANSUY, D .

PURE AND APPLIED CHEMISTRY, 1987, 59 (06) :759-770

[9]

MCCARTHY MB, 1983, J BIOL CHEM, V258, P9153

[10]

MEUNIER B, 1986, B SOC CHIM FR, P578

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