SYNTHESIS AND S-CENTERED REACTIVITY OF (C(5)ME(5))(3)RU3S4+

被引：10

作者：

HOUSER, EJ ^{[1
]}

KRAUTSCHEID, H ^{[1
]}

RAUCHFUSS, TB ^{[1
]}

WILSON, SR ^{[1
]}

机构：

[1] UNIV ILLINOIS, SCH CHEM SCI, URBANA, IL 61801 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001283

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of (C(5)Me(5)Ru+ to (C(5)Me(5))(2)RU(2)S(4) affords (C(5)Me(5))(3)RU(3)S(4)(+); this cluster displays S-centred reactivity towards a range of electrophiles (H+, SO2, Me(+), Et(+)) to give adducts with solid-state structures containing RU(3)(mu(3)-S-2)(mu(3)-S)(mu-SR) cores.

引用

收藏

页码：1283 / 1284

页数：2

相关论文

共 19 条

[1] (CH3C5H4)2V2S4 AS AN ORGANOMETALLIC LIGAND - PREPARATION OF IRON, COBALT, NICKEL, AND IRIDIUM DERIVATIVES AND STRUCTURES OF A V4NI CLUSTER AND 3 V2FE CLUSTERS [J].

BOLINGER, CM ;

WEATHERILL, TD ;

RAUCHFUSS, TB ;

RHEINGOLD, AL ;

DAY, CS ;

WILSON, SR .

INORGANIC CHEMISTRY, 1986, 25 (05) :634-643

[2] THE REACTION OF THE SULFUR-RICH COMPOUNDS (C5ME5)2MO2S4 AND (C5ME5)2CR2S5 WITH M-M DOUBLE BONDING OF THE COMPLEX [ETA-5-C5R5(CO)2M']2 (R=H,CH3 AND M'=CR,MO,W) AND 2-NUCLEAR AND 3-NUCLEAR CLUSTERS WITH M3S4 AND M4S4 STRUCTURES [J].

BRUNNER, H ;

KAUERMANN, H ;

WACHTER, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 265 (02) :189-198

[3] SYNTHESES AND CHARACTERIZATION OF ORGANOMETALLIC MOLYBDENUM IRON SULFUR AND MOLYBDENUM COBALT SULFUR CLUSTERS [J].

COWANS, BA ;

HALTIWANGER, RC ;

DUBOIS, MR .

ORGANOMETALLICS, 1987, 6 (05) :995-1004

[4] STRUCTURE AND CHEMISTRY OF THE COMPLEX TETRAKIS(ETA-5-PENTAMETHYLCYCLOPENTADIENYL)TETRAKIS(MU-3-CHLORO)-TETRARUTHENIUM(II) - A USEFUL PRECURSOR TO (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(0), (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II), AND (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(IV) COMPLEXES [J].

FAGAN, PJ ;

MAHONEY, WS ;

CALABRESE, JC ;

WILLIAMS, ID .

ORGANOMETALLICS, 1990, 9 (06) :1843-1852

[5] CATALYSIS BY TRANSITION-METAL SULFIDES - THE RELATION BETWEEN CALCULATED ELECTRONIC TRENDS AND HDS ACTIVITY [J].

HARRIS, S ;

CHIANELLI, RR .

JOURNAL OF CATALYSIS, 1984, 86 (02) :400-412

[6] NEUTRON-SCATTERING STUDY OF HYDROGEN ON RUTHENIUM SULFIDE [J].

HEISE, WH ;

LU, K ;

KUO, YJ ;

UDOVIC, TJ ;

RUSH, JJ ;

TATARCHUK, BJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (18) :5184-5188

[7] TRINUCLEAR CUBOIDAL AND HETEROMETALLIC CUBANE-TYPE IRON-SULFUR CLUSTERS - NEW STRUCTURAL AND REACTIVITY THEMES IN CHEMISTRY AND BIOLOGY [J].

HOLM, RH .

ADVANCES IN INORGANIC CHEMISTRY, 1992, 38 :1-71

[8] SULFIDO AND RELATED DERIVATIVES OF (C5ME5)RUIII/IV [J].

HOUSER, EJ ;

DEV, S ;

OGILVY, AE ;

RAUCHFUSS, TB ;

WILSON, SR .

ORGANOMETALLICS, 1993, 12 (11) :4678-4681

[9] TETRATHIOMETALATE COMPLEXES OF RHODIUM, IRIDIUM, PALLADIUM, AND PLATINUM - STRUCTURES OF [(C5ME5)RHCL]2WS4 AND [(C3H5)PD]2WS4 [J].

HOWARD, KE ;

RAUCHFUSS, TB ;

WILSON, SR .

INORGANIC CHEMISTRY, 1988, 27 (20) :3561-3567

[10] TRINUCLEAR CLUSTERS OF EARLY TRANSITION-METALS - JAHN-TELLER DISTORTIONS AND ELECTRONIC-STRUCTURE [J].

JIANG, YS ;

TANG, AQ ;

HOFFMANN, R ;

HUANG, JL ;

LU, JX .

ORGANOMETALLICS, 1985, 4 (01) :27-34